Biodiesel production from waste cooking sunflower oil and environmental impact analysis

Authors

  • Mohammed Saifuddin Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603. Kuala Lumpur, Malaysia
  • Amru N. Boyce

Keywords:

Biodiesel, emission, fuel consumption, sunflower oil, viscosity.

Abstract

Waste cooking oil offers great potential as a low cost biodiesel feedstock. Several parameters were tested for the optimumproduction of biodiesel and these included varying the alcohol:oil molar ratios, different catalyst concentrations,temperatures and stirring speed. For the optimum production of biodiesel, the molar ratio of alcohol to oil used was 6:1.The fatty acid methyl esters identified in the biodiesel were methyl palmitate, methyl linoleate, methyloleate and methylstearate. The viscosity of the produced biodiesel was within the range of international ASTM standards. Engine exhaustemission tests of biodiesel showed that the carbon monoxide and unburned hydrocarbon emissions were lower than thatof petrodiesel. The nitrogenous oxides emission and specific fuel consumption were higher than that of conventionaldiesel fuel. It can be concluded that biodiesel produced from waste sunflower oil can be considered as a great potentialsource of commercial biodiesel.

Author Biography

Mohammed Saifuddin, Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603. Kuala Lumpur, Malaysia

I received my Ph.D. degree in Environmental Sciences from University of Malaya, Malaysia. I graduated with a M.Sc. degree by coursework in Chemistry from the University of Chittagong, Bangladesh. From University of Malaya, I did my second M.Sc. degree by research in Biotechnology.

I have published more than 18 papers in peer-reviewed journals with high impact factor and international circulation.

References

review. Brazilian Journal of Chemical Engineering, 29:1-

Bhattia, H.N., Hanifa, M.A., Mohammad, Q. & Rehman, A. (2008).

Biodiesel production from waste tallow. Fuel, 87:2961-2966.

Demirbas, A. (2005). Biodiesel production from vegetable oils via

catalytic and non-catalytic supercritical methanol transesterification

methods. Progress in Energy and Combustion Science, 31:466-487.

Encinar, J.M., Gonzaleza, J.F. & Rodriguez, R.A. (2007). Ethanolysis

of used frying oil. Biodiesel preparation and characterization. Fuel

Processing Technology, 88:513-522.

Guan, G., Kusakabe, K., Sakurai, N. & Moriyama, K. (2008).

Transesterification of vegetable oil to biodiesel fuel using acid catalysts

in the presence of dimethyl ether. Fuel, 88:81-86.

Haseeb, A.S.M.A., Masjuki, H.H., Ann, L.J. & Fazal, M.A. (2010).

Corrosion characteristics of copper and leaded bronze in palm biodiesel.

Fuel Processing Technology, 91:329-333.

Hossain, A.B.M.S., Boyce, A.N., Salleh, A. & Chandran, S. (2010).

Biodiesel production from waste soybean oil biomass as renewable

energy. African Journal of Biotechnology, 9:4233-4240.

Hossain, A.B.M.S. & Boyce, A.N. (2009). Biodiesel production from

waste sunflower cooking oil as an environmental recycling process and

renewably energy. Bulgarian Journal of Agricultural Science, 15:312-

Hossain, A.B.M.S., Aishah, S., Amru, N.B., Partha, P. & Mohd, N.

(2008). Bioethanol production from agricultural waste as a renewable

bioenergy resource in biomaterials. 4th Kuala Lumpur International

Conference on Biomedical Engineering 2008. IFMBE Proceedings,

:300-305.

Knothe, G. & Steidley, K.R. (2005). Kinematic viscosity of biodiesel

fuel components and related compounds. Influence of compound

structure and comparison to petrodiesel fuel components. Fuel,

:1059–1065.

Korn, M., Santos, D.S., Welz, B., Vale, M.G., Teixeira, A.P. &

Limaa, D. (2007). Atomic spectrometric methods for the determination

of metals and metalloids in automotive fuels – A review. Talanta,73:1-

Lei, Z., Cheung, C.S., Zhang, W.G. & Zhen, H. (2010). Emissions

characteristics of a diesel engine operating on biodiesel and biodiesel

blended with ethanol and methanol. Science of the Total Environment,

:914–921.

Leung, D.Y.C., Koo, B.C.P. & Guo, Y. (2006). Degradation of

biodiesel under different storage conditions. Bioresource Technology,

:250-256.

Lina, C.Y., Lina, H.A. & Hungb, L.B. (2006). Fuel structure and

properties of biodiesel produced by the peroxidation process. Fuel,

:1743-1749.

Lisboa, P., Rodrigues, A.R., Martín, J.L., Simões, P., Barreiros,

S. & Paiva, A. (2014). Economic analysis of a plant for biodiesel

production from waste cooking oil via enzymatic transesterification

using supercritical carbon dioxide. The Journal of Supercritical Fluids,

:31-40.

Ma, F. & Hanna, M.A. (1999). Biodiesel production: a review.

Bioresource Technology, 70:1-15.

Mohamed, Y.E.S. (2009). Reducing the viscosity of Jojoba methyl ester

diesel fuel and effects on diesel engine performance and roughness.

Energy Conversion and Management, 50:1781-1788.

Nezihe, A. & Aysegul, D. (2007). Alkali catalyzed transesterification of

cottonseed oil by microwave irradiation. Fuel, 86:2639-2644.

Pugazhvadivu, M. & Jeyachandran, K. (2005). Investigations on the

performance and exhaust emissions of a diesel engine using preheated

waste frying oil as fuel. Renewable Energy, 30:2189-2202.

Rhamadhas, A.S., Muraleedharan, C. & Jayaraj, S. (2005).

Performance and emission evaluation of a diesel engine fuelled with

methyl esters of rubber seed oil. Renewable Energy, 30:1789-1800.

Saifuddin, M., Goh, P.E., Ho, W.S., Moneruzzaman K.M. &

Nasrulhaq-Boyce, A. (2014a). Biodiesel production from waste

cooking palm oil and environmental impact analysis. Bulgarian Journal

of Agricultural Sciences, 20:186-192.

Saifuddin, M., Moneruzzaman, K.M., Hossain, A.B.M.S., Sarwar,

M.J., Nashriyah, B.M., et al. (2014b). Bioethanol production from

Mango Waste (Mangifera indica L. cv chokanan): biomass as renewable

energy. Australian Journal of Basic and Applied Sciences, 8:229-237.

Sheinbaum-Pardo, C., Calderón-Irazoque, A. & Ramírez-Suárez,

M. (2013). Potential of biodiesel from waste cooking oil in Mexico.

Biomass and Bioenergy, 56:230-238.

Somporn, P. & Shabbir, H.G. (2009). Full chain energy analysis

of biodiesel production from palm oil in Thailand. Applied Energy,

:209-214.

Steven, L. & Lee, K.T. (2010). Recent trends, opportunities and

challenges of biodiesel in Malaysia: an overview. Renewable and

Sustainable Energy Reviews, 14:938-954.

Wisniewski, A.J., Wiggers, V.R., Simionatto, E.L., Meier, H.F.,

Barros, A.A.C., et al. (2010). Biofuels from waste fish oil pyrolysis:

chemical composition. Fuel, 89:563-568.

Woods, G.D. & Fryer, F.I. (2007). Direct elemental analysis of

biodiesel by inductively coupled plasma-mass spectrometry. Analytical

and Bioanalytical Chemistry, 389:753–761.

Wyatt, T., Seth, M. & Travis, G. (2010). The U.S. biodiesel use

mandate and biodiesel feedstock markets. Biomass and Bioenergy,

:883-889.

Xiangmei, M., Guanyi, C. & Yonghong, W. (2008). Biodiesel

production from waste cooking oil via alkali catalyst and its engine

test. Fuel Processing Technology, 89:851-857.

Yaakob, Z., Mohammad, M., Alherbawi, M., Alam, Z. & Sopian,

K. (2013). Overview of the production of biodiesel from waste cooking

oil. Renewable and Sustainable Energy Reviews, 18:184-193.

Zhang, Y., Dube. M.A., Mclean, D.D. & Kates, M. (2003). Biodiesel

production from waste cooking oil: Economic assessment and sensitivity

analysis. Bioresource Technology, 90:229-240.

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Published

08-08-2016