Mineralogical characteristics of surface sediment in Sulaibikhat Bay, Kuwait

Authors

  • HASSAN ALSHEMMARI Environmental Science Department, Kuwait Institute for Scientific Research
  • ALI M. AL-DOUSARI Environmental Science Department, Kuwait Institute for Scientific Research
  • LINA TALEBI Environmental Science Department, Kuwait Institute for Scientific Research
  • ABDUL NABI AL-GHADBAN Environmental Science Department, Kuwait Institute for Scientific Research

Keywords:

Grain sizes, sediment, aragonite, pyrite

Abstract

Surface sediment samples were collected from 35 locations in Sulaibikhat Bay, Kuwait. Grain sizes, total organic carbon (TOC), carbonate and mineralogical data were determined. The geographical distribution of these parameters, and their relationships with each other are described. Grain-size analysis showed a high positive correlation between clay minerals and organic matter (measured as TOC), but a high negative correlation between clay minerals and carbonate content (measured as CaCO3). Grain-size analysis also showed that the southeastern part of the Bay, which contains muddy sediments with a predominant silt fraction, also has the highest clay content. The calcium carbonate in the sediments, particularly in the western part of the Bay, is composed of sand-sized biogenic calcareous fragments of aragonite. There appears to be a positive relationship between coarse-grained sediments and the biogenic content of bottom sediments in the Bay. This study shows that there is an abundance of carbonate, clay minerals, feldspar, pyrite, gypsum and muscovite in different particular parts of the Bay. An abundance of pyrite close to the Ghazali outfall with low oxidation-reduction potential (ORP) values (48.0-188 mV) may be associated with the presence of hydrogen sulphide and pyrite in the sediments suggest the possibility that reducing conditions prevail because of sulphate reduction associated with the decomposition of organic matter. The high correlation of pyrite with TOC supports the view that the presence of pyrite is an indicator of the presence of sewage waste under anaerobic conditions.

References

Al-Bakri, D. 1996. A geomorphological approach to sustainable planning and management of the Coastal Zone of Kuwait. Geomorphology 17: 323-337.

Al-Bakri, D., Khalaf, G. Shublaq, W. 1984. Shoreline change and its impact on the coastal environment in Kuwait. Annual Research Report: Kuwait Institute for Scientific Research.

Al-Dousari, A. M. Al-Awadhi, J. 2012. Dust fallout characteristics within global dust storms major trajectories. Arabian Journal of Geosciences, DOI: 10.1007/s12517-012-0644-0.

Al-Ghadban, A. N. El-Sammak, A. 2005. Sources, distribution and composition of the suspended sediments, Kuwait Bay, Northern Arabian Gulf. Journal of Arid Environments 60: 647-661.

Al-Ghadban, A. N., Abdali, F. Massoud, M. S. 1998. Sedimentation rate and bioturbation in the Arabian Gulf. Environment International 24: 23-31.

Al-Ghadban, A., Al-Majed, N. Al-Muzaini, S. 2002. The state of marine pollution in Kuwait: Northern Arabian Gulf. Technology 8: 7-26.

Al-Muzaini, S. 2002. Sewage discharge impact on the development of the Shuwaikh. Technology 8: 51-54.

Al-Sarawi, M. A., Massoud, M. S., Khader, S. R. Bou-Olyan, A. H. 2002. Recent trace metal levels in coastal water of Sulaibikhat Bay, Kuwait. Technology 8: 27-38.

Alshemmari, H. 2009. Prediction of element speciation in sediments from Sulaibikhat Bay, Kuwait. Ph.D. Thesis, Newcastle University.

Alshemmari, H., Al Otaibi, Y. Owens, R. 2010. Trace metal concentrations in the surface sediments of Sulaibikhat Bay, Kuwait. Kuwait Journal of Science and Engineering 37: 87-110.

Dames Moore, 1983. Studies for Sabiya area, Kuwait Bay and development of electrical networks. Aquatic Biology Investigations. Ministry of Electricity and Water, Government of Kuwait.

Hardy, R. G. Tucker, M. E. 1988. X-ray powder diffraction of sediments. In: M.E. Tucker (Ed.), Techniques in Sedimentology, Blackwell Scientific Publications, Oxford.

Horowitz, A. J. 1991. A Primer on Sediment-Trace Element Chemistry. Lewis Publishers, Michigan, USA.

Jackson, M. Barak, P. 2005. Soil Chemical Analysis: Advanced Course. UW-Madison Libraries Parallel Press, 930 p., ISBN 1893311473, ISBN-13: 9781893311473.

Keil, R. G., Tsamakis, E., Fuh, C. B., Giddings J. C. Hedges, J. I. 1994. Mineralogical and textural controls on the organic composition of coastal marine sediments: hydrodynamic separation using SPLITT-fraction. Geochimica et Cosmochimica Acta 58: 879-893.

Khalaf, F. Al-Hashash, M. 1983. Aeolian sedimentation in the north western part of the Arabian Gulf. Journal of Arid Environments 6: 319-332.

Khan, N. Y., Saeed, T., Al-Ghadban, A. N., Beg, M. U., Jacob, P. G., Al-Dousari, A. M., Al-Shemmari, H., Al-Mutari, M., Al-Obaid, T. Al-Matrouk, K. 1999. Assessment of sediment quality in Kuwait's Territorial Waters. Phase 1: Kuwait Bay. Kuwait Institute for Scientific Research.

Kim, Y., Cho, S., Kang, H. D., Kim, W., Lee, H. R., Doh, S. H., Kim, K., Yun, S. G., Kim D. S. Jeong, G. Y. 2006. Radiocesium reaction with illite and organic content in marine sediment. Marine Pollution Bulletin 52: 659-665.

Kim, Y., Kim, K., Kang, H. D., Kim, W., Doh, S. H., Kim D. S. Kim, B. K. 2007. The accumulation of radiocesium in coarse marine sediment: Effects of mineralogy and organic content. Marine Pollution Bulletin 54: 1341-1350.

Mayer, L. M. 1994. Relationships between mineral surfaces and organic carbon concentrations in soils and sediments, Chemical Geology 114: 347-363.

MOOPAM (Manual of Oceanographic Observations and Pollutant Analyses Methods). 1999. The Regional Organization for the Protection of the Marine Environment (3rd Edition). Kuwait.

Rubio, B., Nombelia, M. A. Vilas, F. 2000. Geochemistry of major and trace elements in sediments of the Ria De Vigo (NW Spain): An assessment of metal pollution. Marine Pollution Bulletin 40: 968-980.

Scholz, F. Neumann, T. 2007. Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea. Marine Chemistry 107: 16-532.

UNESCO/WHO/UNEP 1996. Selection of Water Quality Variables. In: Chapman, D. (Ed.). Water Quality Assessments - A Guide to Use of Biota (2nd Edition); Chapter 3, Sediments and Water in Environmental Monitoring. ISBN 0 419 21590 5.

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Published

26-09-2013

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Earth & Environment